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KMID : 1059519910350050553
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Journal of the Korean Chemical Society
1991 Volume.35 No. 5 p.553 ~ p.559
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Study on the Ion Exchange Mechanisms of Rare Earth Elements in Several Elution Types (II)
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Cha Ki-Won
Hong Sung-Wook
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Abstract
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The elution characteristics of rare earth elements in NH4+ form cation exchange resin had been investigated. Elution were performed varing the loading amount, column diameter, column length and eluent pH. Analysing the chemical species contained in each effluent, elution mechanisms of rare earth elements and the separation of rare earth elements in monazite could be understood. The resolution values of adjacent rare earth elements were improved increasing rare earths adsorption amount wfith the same column within it's exchange capacity. With NH4+ resin form, column length does not affect on the resolution values and retention time of rare earth elements and the rare earth-EDTA complex were not adsorbed on NH4+ resin form. pH of eluent affected on the reactivities between rare earth elements and EDTA. Decreasing eluent pH, resolution values of adjacent rare earth elements were increased while increasing elution time.
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KEYWORD
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